This is a collection of input and output files that were used to produce all the data reported in the following publication: G. Gebreyesus, L. Bastonero, M. Kotiuga, N. Marzari, I. Timrov, "Understanding the role of Hubbard corrections in the rhombohedral phase of BaTiO3", accepted in Phys. Rev. B (2023); arXiv:2309.04348. Calculations were performed using: - The open-source Quantum ESPRESSO distribution (version 7.1) which can be downloaded from www.quantum-espresso.org. The following codes of Quantum ESPRESSO were used: pw.x - the code that performs self-consistent-field (SCF) ground-state calculations (to obtain total energy, forces, stress, and other properties) using Hubbard-corrected density-functional theory (DFT+U and DFT+U+V); hp.x - the code that computes the Hubbard U and V parameters using density-functional perturbation theory (DFPT); dos.x - the code to compute the total density of states (DOS); projwfc.x - the code to compute the projected density of states (PDOS). - The open-source Phonopy package (version 2.7.1) which can be downloaded from https://phonopy.github.io/phonopy/ DESCRIPTION AND CONTENT OF FOLDERS: /QuantumESPRESSO - /1_Self-consistent_calculation_of_Hubbard_parameters (calculation of Hubbard parameters and structural optimization) - /Calculation_of_U /U-on-Ti-3d /U-on-Ti-3d-and-O-2p - /Calculation_of_U_and_V /U-on-Ti-3d_and_V_Ti3d-O2p /U-on-Ti-3d-and-O-2p_and_V_Ti3d-O2p These folders contain the following files: * BaTiO3.scf.in - input file for the SCF calculation using pw.x * BaTiO3.scf.out - output file from the SCF calculation using pw.x * BaTiO3.hp.in - input file for the Hubbard U and V parameters calculations using hp.x * BaTiO3.hp.out - output file from the the Hubbard U and V parameters calculations using hp.x * BaTiO3.Hubbard_parameters.dat - a file that contains the computed values of U and V * HUBBARD.dat - a file that contains the computed values of U and V that is used in in the “HUBBARD” card in BaTiO3.scf.in. * BaTiO3.vc-relax.in - input file for vc-relax calculations using pw.x * BaTiO3.vc-relax.out - output file from vc-relax calculation using pw.x - /2_Structural_properties (optimized 'a' and 'alpha' as a function of U) -/U=0.0 -/U=0.5 -/U=1.0 -/U=1.5 -/U=2.0 -/U=2.5 -/U=3.0 -/U=3.5 -/U=4.0 -/U=4.5 -/U=5.0 -/U=4.5160 -/U=5.5 -/U=6.0 -/U=7.0 -/U=8.0 -/U=9.0 -/U=10.0 * BTO.vcrelax.in - input file for vc-relax calculations using pw.x * BTO.vcrelax.out - output file from vc-relax calculation using pw.x - /3_PDOS (projected density of states) - /PDOS_PBEsol - /PDOS_PBEsol+U - /PDOS_PBEsol+U+V These folders contain the following files: * BaTiO3.scf.in - input file for the SCF calculation using pw.x * BaTiO3.scf.out - output file from the SCF calculation using pw.x * BaTiO3.pdos.in - input file for the PDOS calculation using projwfc.x * BaTiO3.pdos.out - output file from the PDOS calculation using projwfc.x * BaTiO3.pdos_tot - output file containing the DOS and summed PDOS * BaTiO3.pdos_atm#*(*)_wfc#*(*) - output files from projwfc.x with the PDOS for each orbital of each atom /Phonopy The phonons are computed using the optimized struture (for PBEsol+U is a cubic phase). The phonons at Gamma and the phonon dispersions computed using Phonopy employing the following commands: *phonopy --qe -d --dim="1 1 1" -c BTO.scf.in - to create a 1x1x1 cell (eight cells with displacements are created). *phonopy --qe -d --dim="3 3 3" -c BTO.scf.in - to create a 3x3x3 supercell (eight supercells with displacements are created). *phonopy -f BaTiO3-001.out BaTiO3-002.out BaTiO3-003.out BaTiO3-004.out BaTiO3-005.out BaTiO3-006.out BaTiO3-007.out BaTiO3-008.out *phonopy --qe -c BaTiO3.scf.in -p band.conf -/PBEsol -/1x1x1 -/001 -/002 -/003 -/004 -/005 -/006 -/007 -/008 -/3x3x3 -/001 -/002 -/003 -/004 -/005 -/006 -/007 -/008 -/PBEsol+U -/1x1x1 -/001 -/002 -/003 -/004 -/005 -/006 -/007 -/008 -/3x3x3 -/001 -/002 -/003 -/004 -/005 -/006 -/007 -/008 -/PBEsol+U+V -/1x1x1 -/001 -/002 -/003 -/004 -/005 -/006 -/007 -/008 -/3x3x3 -/001 -/002 -/003 -/004 -/005 -/006 -/007 -/008 -/PBEsol+U+V@PBEsol_geometry -/1x1x1 -/001 -/002 -/003 -/004 -/005 -/006 -/007 -/008 These folders contain the following files: * BTO.scf-00#.in - Supercells input files for the SCF calculations to obtain force on atoms (# is for each atomic displacement. In this case, it runs from 1 - 8) using pw.x * BTO.scf-00#.out - Supercells output files containing the force on atoms (# is for each atomic displacement. In this case, it runs from 1 - 8) from the SCF calculations using pw.x /Pseudopotentials (folder containing pseudopotentials) Pslibrary v1.0.0 - Ba.pbesol-spn-rrkjus_psl.1.0.0.UPF - pseudopotential for Ba - Ti.pbesol-spn-rrkjus_psl.1.0.0.UPF - pseudopotential for Ti - O.pbesol-n-rrkjus_psl.1.0.0.UPF - pseudopotential for O /Figures (folder with the source figures) - Fig2.xmgr - Xmgrace figure 2 (structural properties) - Fig3.xmgr - Xmgrace figure 3 (projected density of states) - Fig4a.xmgr - Xmgrace figure 4a (phonon dispersion, rhombohedral BTO) - Fig4b.xmgr - Xmgrace figure 4b (phonon dispersion, rhombohedral BTO) - Fig5.xmgr - Xmgrace figure 5 (phonon dispersion, cubic BTO) - Fig6.xmgr - Xmgrace figure 6 (Raman spectrum)