This directory contains all data necessary to reporduce the figures and tables of the paper. In particular: ./Fig. 1 contains the data related to Figure 1 in the manuscript and Fig. S5 and S7 in the Supplementary Information. ./Fig. 2 contains the data related to Figure 2 in the manuscript. ./Fig. 3 contains the data related to Figure 3 in the manuscript. ./Fig. 4 contains the data related to Figure 4 in the manuscript. ./Fig. 5 contains the data related to Figure 5 in the manuscript and Fig. S44 in the Supplementary Information. ./SI-1 contains the thermal gravity analysis (TGA), differential scanning calorimeter (DSC) characterization, cyclic voltammograms (CV), absorption spectra, fluorescence spectroscopy and PDS spectra . ./SI-2 contains the data related to the GIWAXS characterization, paracrystalline disorder and infrared absorption spectra. ./SI-3 contains the raw data of XPS characterization and AC Hall measurement. ./SI-4 contains the data related to the FET characterization, conductivities, EPR characterization, activation energy and the time-dependent decay of the electrical conductivities. ./SI-5 contains the data related to the DFT calculations and Molecular dynamics(MD) calculations. ./SI-6 contains the raw data of the NMR spectra of the organic intermediates and the polymers, the mass spectrometry data of some organic intermediates.