This file is automatically generated. It contains the descriptions of each uploaded file as provided by the user.

• Fig. 1.zip: Fig. 1 contains the data related to Figure 1 in the manuscript and Fig. S5 and S7 in the Supplementary Information.
• Fig. 2.zip: Fig. 2 contains the data related to Figure 2 in the manuscript.
• Fig. 3.zip: Fig. 3 contains the data related to Figure 3 in the manuscript.
• Fig. 4.zip: Fig. 4 contains the data related to Figure 4 in the manuscript.
• Fig. 5.zip: Fig. 5 contains the data related to Figure 5 in the manuscript and Fig. S44 in the Supplementary Information.
• SI-1.zip: SI-1 contains the thermal gravity analysis (TGA), differential scanning calorimeter (DSC) characterization, cyclic voltammograms (CV), absorption spectra, fluorescence spectroscopy and PDS spectra .
• SI-2.zip: SI-2 contains the data related to the GIWAXS characterization, paracrystalline disorder and infrared absorption spectra.
• SI-3.zip: SI-3 contains the raw data of XPS characterization and AC Hall measurement.
• SI-4.zip: SI-4 contains the data related to the FET characterization, conductivities, EPR characterization, activation energy and the time-dependent decay of the electrical conductivities.
• SI-5.zip: SI-5 contains the data related to the DFT calculations and Molecular dynamics(MD) calculations.
• SI-6.zip: SI-6 contains the raw data of the NMR spectra of the organic intermediates and the polymers, the mass spectrometry data of some organic intermediates.
• README.txt: a short description of the files