Microscopic nature of the charge-density wave in the kagome superconductor RbV₃Sb₅
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{
"id": "2076",
"updated": "2024-02-05T15:03:30.697263+00:00",
"metadata": {
"version": 1,
"contributors": [
{
"givennames": "Jonathan",
"affiliations": [
"Dipartimento di Fisica e Astronomia, Universit\u00e0 di Bologna, Viale Berti-Pichat 6/2, 40127 Bologna, Italy"
],
"familyname": "Frassineti"
},
{
"givennames": "Pietro",
"affiliations": [
"Dipartimento di Scienze Matematiche, Fisiche e Informatiche, Universit\u00e0 di Parma, Parco Area delle Scienze 7/A, I-43124 Parma, Italy"
],
"email": "pietro.bonfa@unipr.it",
"familyname": "Bonf\u00e0"
},
{
"givennames": "Giuseppe",
"affiliations": [
"Dipartimento di Scienze Matematiche, Fisiche e Informatiche, Universit\u00e0 di Parma, Parco Area delle Scienze 7/A, I-43124 Parma, Italy"
],
"familyname": "Allodi"
},
{
"givennames": "Erik",
"affiliations": [
"Department of Physics, Brown University, Providence, Rhode Island 02912, USA"
],
"familyname": "Garcia"
},
{
"givennames": "Rong",
"affiliations": [
"Department of Physics, Brown University, Providence, Rhode Island 02912, USA"
],
"familyname": "Cong"
},
{
"givennames": "Brenden R.",
"affiliations": [
"Materials Department and California Nanosystems Institute, University of California Santa Barbara, Santa Barbara, California 93106, USA"
],
"familyname": "Ortiz"
},
{
"givennames": "Stephen D.",
"affiliations": [
"Materials Department and California Nanosystems Institute, University of California Santa Barbara, Santa Barbara, California 93106, USA"
],
"familyname": "Wilson"
},
{
"givennames": "Roberto",
"affiliations": [
"Dipartimento di Scienze Matematiche, Fisiche e Informatiche, Universit\u00e0 di Parma, Parco Area delle Scienze 7/A, I-43124 Parma, Italy"
],
"familyname": "De Renzi"
},
{
"givennames": "Vesna F.",
"affiliations": [
"Department of Physics, Brown University, Providence, Rhode Island 02912, USA"
],
"familyname": "Mitrovi\u0107"
},
{
"givennames": "Samuele",
"affiliations": [
"Dipartimento di Fisica e Astronomia, Universit\u00e0 di Bologna, Viale Berti-Pichat 6/2, 40127 Bologna, Italy"
],
"familyname": "Sanna"
}
],
"title": "Microscopic nature of the charge-density wave in the kagome superconductor RbV\u2083Sb\u2085",
"_oai": {
"id": "oai:materialscloud.org:2076"
},
"keywords": [
"Kagome Metal RbV3Sb5",
"DFT",
"Nuclear Magnetic Resonance",
"Nuclear Quadrupole Resonance"
],
"publication_date": "Feb 05, 2024, 16:03:30",
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"references": [
{
"comment": "Manuscript where the data is discussed",
"doi": "10.1103/PhysRevResearch.5.L012017",
"citation": "Phys. Rev. Research 5, L012017 (2023)",
"url": "https://doi.org/10.1103/PhysRevResearch.5.L012017",
"type": "Journal reference"
}
],
"description": "The recently discovered vanadium-based Kagome metals AV\u2083Sb\u2085 (A = K, Rb, Cs) undergo a unique phase transition into charge-density wave (CDW) order which precedes both unconventional superconductivity and time-reversal symmetry breaking. Therefore the essential first step in building a full understanding of the role of CDW in establishing these unconventional phases is to unveil the symmetries and the microscopic nature of the charge-ordered phase. Here, we determine the exact structure of the 2\u00d72\u00d72 superlattice that develops below the charge-density wave ordering temperature (TCDW) in RbV\u2083Sb\u2085. We present a comprehensive set of \u2075\u00b9V, \u2078\u2077Rb, and \u00b9\u00b2\u00b9Sb nuclear magnetic resonance (NMR) measurements and density functional theory simulations of NMR observables to provide a unique site-selective view into the local nature of the charge-ordered phase. The combination of these experimental results with simulations provides compelling evidence that the CDW structure prevailing below 103 K in RbV\u2083Sb\u2085 is the so-called inverse Star of David pattern, \u03c0-shifted along the c axis. These findings put severe constraints on the topology of these Kagome compounds and thus provide essential guidance for the development of an appropriate theoretical framework for predicting properties of exotic electronic orders arising within the CDW phase.",
"status": "published",
"license": "Creative Commons Attribution Share Alike 4.0 International",
"conceptrecid": "2075",
"is_last": true,
"mcid": "2024.22",
"edited_by": 576,
"id": "2076",
"owner": 80,
"license_addendum": null,
"doi": "10.24435/materialscloud:n0-va"
},
"revision": 4,
"created": "2024-02-05T10:48:25.241206+00:00"
}