Synthesis and Characterization of π-Extended Triangulene

JSON Export

{
  "revision": 1, 
  "id": "224", 
  "created": "2020-05-12T13:53:16.318249+00:00", 
  "metadata": {
    "doi": "10.24435/materialscloud:2019.0062/v1", 
    "status": "published", 
    "title": "Synthesis and Characterization of \u03c0-Extended Triangulene", 
    "mcid": "2019.0062/v1", 
    "license_addendum": "", 
    "_files": [
      {
        "description": "tar file containing all data", 
        "key": "data.tgz", 
        "size": 24844192, 
        "checksum": "md5:aae1e673b2091113724c55926bf301a7"
      }, 
      {
        "description": "README file in yaml format detailing the content of the record", 
        "key": "ReadMe.yaml", 
        "size": 35736, 
        "checksum": "md5:2bfba87bd2dd850eebe49fee1c00db93"
      }, 
      {
        "description": "example of jupyter notebook to read the README.yaml file, extract files from the tar\r\nand plot the raw version of experimental images", 
        "key": "Read_YAML.ipynb", 
        "size": 14803, 
        "checksum": "md5:0b0f0b7becf356e28bc102f693d2a2b0"
      }
    ], 
    "owner": 26, 
    "_oai": {
      "id": "oai:materialscloud.org:224"
    }, 
    "keywords": [
      "MARVEL/DD3", 
      "Non-Kekul\u00e9 ", 
      "nanographenes", 
      "on-surface synthesis", 
      "triangulene"
    ], 
    "conceptrecid": "223", 
    "is_last": true, 
    "references": [
      {
        "type": "Journal reference", 
        "doi": "10.1021/jacs.9b05319", 
        "url": "", 
        "comment": "Manuscript where the results are discussed", 
        "citation": "S. Mishra, D. Beyer, K. Eimre, J. Liu, R. Berger, O. Gr\u00f6ning, C. A. Pignedoli, K. M\u00fcllen, R. Fasel, X. Feng, P. Ruffieux  J. Am. Chem. Soc. 141 (27), 10621-10625 (2019). "
      }
    ], 
    "publication_date": "Oct 21, 2019, 00:00:00", 
    "license": "Creative Commons Attribution 4.0 International", 
    "id": "224", 
    "description": "In a recent work, we reported a combined in-solution and on-surface synthesis of \u03c0-extended triangulene, a non-Kekul\u00e9 nanographene with the structural formula C33H15, consisting of ten benzene rings fused in a triangular fashion. The distinctive topology of the molecule entails the presence of three unpaired electrons that couple to form a spin quartet ground state. In this record we include experimental and computational data that support the findings of the manuscript.", 
    "version": 1, 
    "contributors": [
      {
        "email": "shantanu.mishra@empa.ch", 
        "affiliations": [
          "nanotech@surfaces Laboratory, Empa \u2212 Swiss Federal Laboratories for Materials Science and Technology, 8600 D\u00fcbendorf, Switzerland"
        ], 
        "familyname": "Mishra", 
        "givennames": "Shantanu"
      }, 
      {
        "affiliations": [
          "Faculty of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technical University of Dresden, 01069 Dresden, Germany"
        ], 
        "familyname": "Beyer", 
        "givennames": "Doreen"
      }, 
      {
        "email": "kristjan.eimre@empa.ch", 
        "affiliations": [
          "nanotech@surfaces Laboratory, Empa \u2212 Swiss Federal Laboratories for Materials Science and Technology, 8600 D\u00fcbendorf, Switzerland"
        ], 
        "familyname": "Eimre", 
        "givennames": "Kristjan"
      }, 
      {
        "affiliations": [
          "Faculty of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technical University of Dresden, 01069 Dresden, Germany"
        ], 
        "familyname": "Liu", 
        "givennames": "Junzhi"
      }, 
      {
        "affiliations": [
          "Faculty of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technical University of Dresden, 01069 Dresden, Germany"
        ], 
        "familyname": "Berger", 
        "givennames": "Reinhard"
      }, 
      {
        "affiliations": [
          "nanotech@surfaces Laboratory, Empa \u2212 Swiss Federal Laboratories for Materials Science and Technology, 8600 D\u00fcbendorf, Switzerland"
        ], 
        "familyname": "Gro\u0308ning", 
        "givennames": "Oliver"
      }, 
      {
        "affiliations": [
          "nanotech@surfaces Laboratory, Empa \u2212 Swiss Federal Laboratories for Materials Science and Technology, 8600 D\u00fcbendorf, Switzerland"
        ], 
        "familyname": "Pignedoli", 
        "givennames": "Carlo A."
      }, 
      {
        "affiliations": [
          "Department of Synthetic Chemistry, Max Planck Institute for Polymer Research, 55021 Mainz, Germany"
        ], 
        "familyname": "Mu\u0308llen", 
        "givennames": "Klaus"
      }, 
      {
        "affiliations": [
          "nanotech@surfaces Laboratory, Empa \u2212 Swiss Federal Laboratories for Materials Science and Technology, 8600 D\u00fcbendorf, Switzerland", 
          "Department of Chemistry and Biochemistry, University of Bern, 3012 Bern, Switzerland"
        ], 
        "familyname": "Fasel", 
        "givennames": "Roman"
      }, 
      {
        "affiliations": [
          "Faculty of Chemistry and Food Chemistry, and Center for Advancing Electronics Dresden, Technical University of Dresden, 01069 Dresden, Germany"
        ], 
        "familyname": "Feng", 
        "givennames": "Xinliang"
      }, 
      {
        "email": "pascal.ruffieux@empa.ch", 
        "affiliations": [
          "nanotech@surfaces Laboratory, Empa \u2212 Swiss Federal Laboratories for Materials Science and Technology, 8600 D\u00fcbendorf, Switzerland"
        ], 
        "familyname": "Ruffieux", 
        "givennames": "Pascal"
      }
    ], 
    "edited_by": 98
  }, 
  "updated": "2019-10-21T00:00:00+00:00"
}