Published February 3, 2019
| Version v1
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Double helix PBDT polymer - Submitted manuscript, simulations and other source data
Creators
- 1. Department of Chemistry and Macromolecules Innovation Institute, Virginia Tech, Blacksburg, Virginia 24061, United States
- 2. Department of Mechanical Engineering, Virginia Tech, Blacksburg, Virginia 24061, United States
- 3. Department of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, 2629 HS, Delft, The Netherlands
- 4. Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands
- 5. Department of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, 2629 HS, Delft, The Netherlands; Department of Applied Physical Sciences, University of North Carolina at Chapel Hill, 121 South Road, Chapel Hill, NC27599-3050, United States
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Description
We describe a double helical conformation in the densely charged aromatic polyamide poly(2,2'- disulfonyl-4,4'-benzidine terephthalamide) or PBDT. This double helix macromolecule represents one of the most rigid simple molecular structures known, exhibiting an extremely high axial persistence length (~ 1 micrometer).
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References
Journal reference Y. Wang et al., Nat. Commun. 2019