Collective all‐carbon magnetism in triangulene dimers
Creators
- 1. nanotech@surfaces Laboratory, Empa-Swiss Federal Laboratories for Materials Science and Technology, 8600 Dübendorf, Switzerland
- 2. Center for Advancing Electronics and Department of Chemistry and Food Chemistry, Technical University of Dresden, 01062 Dresden, Germany
- 3. Department of Applied Physics, University of Alicante, 03690 Sant Vicent del Raspeig, Spain
- 4. Department of Chemical Physics, University of Alicante, 03690 Sant Vicent del Raspeig, Spain
- 5. QuantaLab, International Iberian Nanotechnology Laboratory, 4715-330 Braga, Portugal
- 6. Department of Chemistry and Biochemistry, University of Bern, 3012 Bern, Switzerland
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Description
This record contain data to support the result we published in the work "Collective All‐Carbon Magnetism in Triangulene Dimers". Triangular zigzag nanographenes, such as triangulene and its π‐extended homologues, have received widespread attention as organic nanomagnets for molecular spintronics, and may serve as building blocks for high‐spin networks with long‐range magnetic order, which are of immense fundamental and technological relevance. In the publication we present the on‐surface synthesis and a proof‐of‐principle experimental study of magnetism in covalently bonded triangulene dimers. On‐surface reactions of rationally designed precursor molecules on Au(111) lead to the selective formation of triangulene dimers in which the triangulene units are either directly connected through their minority sublattice atoms, or are separated via a 1,4‐phenylene spacer.
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References
Journal reference (Manuscript where the results are discussed) S. Mishra, D. Beyer, K. Eimre, R. Ortiz, J. Fernández-Rossier, R. Berger, O. Gröning, C. Pignedoli, R. Fasel, X. Feng, P. Ruffieux, Angew. Chem. Int. Ed. 59, 12041 - 12047 (2020), doi: 10.1002/anie.202002687
Journal reference (Manuscript where the results are discussed) S. Mishra, D. Beyer, K. Eimre, R. Ortiz, J. Fernández-Rossier, R. Berger, O. Gröning, C. Pignedoli, R. Fasel, X. Feng, P. Ruffieux, Angew. Chem. Int. Ed. 59, 12041 - 12047 (2020)