Qiang Sun^1*, Ian Cheng-Yi Hou², Kristjan Eimre¹, Carlo A. Pignedoli^1*, Pascal Ruffieux^1*, Akimitsu Narita^2,3*, Roman Fasel^1,4*

1 nanotech@surfaces Laboratory, Empa, Swiss Federal Laboratories for Materials Science and Technology, 8600 Dübendorf, Switzerland

2 Max Planck Institute for Polymer Research, 55128 Mainz, Germany

3 Organic and Carbon Nanomaterials Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna-son, Kunigami, Okinawa 904-0495, Japan

4 Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland

* Corresponding authors emails: qiang.sun@empa.ch, carlo.pignedoli@empa.ch, pascal.ruffieux@empa.ch, narita@mpip-mainz.mpg.de, roman.fasel@empa.ch

DOI10.24435/materialscloud:zt-m2 [version v1]

Publication date: Jul 15, 2020

How to cite this record

Qiang Sun, Ian Cheng-Yi Hou, Kristjan Eimre, Carlo A. Pignedoli, Pascal Ruffieux, Akimitsu Narita, Roman Fasel, On-surface synthesis of polyazulene with 2,6-connectivity, Materials Cloud Archive 2020.76 (2020), https://doi.org/10.24435/materialscloud:zt-m2

Description

Azulene, the smallest neutral nonalternant aromatic hydrocarbon, serves not only as a prototype for fundamental studies but also as a versatile building block for functional materials because of its unique opto(electronic) properties. The record contains data to support our recent work where we report the on-surface synthesis and characterization of the homopolymer of azulene connected exclusively at the 2,6-positions using 2,6-diiodoazulene as the monomer precursor. Properties of carbon-based aromatic systems are sensitively determined by their bond topologies. So far, much attention has been paid to the design and synthesis of aromatic materials like conjugated polymers and nanographenes constituted by alternant hydrocarbons, which do not possess odd-membered rings. In contrast, incorporation of non-alternant hydrocarbons has only rarely been explored.

Materials Cloud sections using this data

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File name	Size	Description
ReadMe.yaml MD5md5:24dd76ae808ba98f73cbb057fdf46703	18.0 KiB	ReadMe file in yaml format describing the list of files
data.tgz MD5md5:ba7c79d7bf62d03c09bf99daa08b7f09	11.6 MiB	tar file containing files described in ReadME.yaml
calculations_figs_3c_4c_S4_S5.aiida MD5md5:8286ba6e977f444a5fdf5de15fb41871 Open this AiiDA archive on renkulab.io (https://renkulab.io/)	1.0 GiB	AiiDA archive with nodes for different calculations

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External references

Keywords

MARVEL/DD3 SNSF ab initio on surface synthesis azulene