Publication date: Dec 14, 2019
The origin of the metal-to-insulator transition (MIT) in RNiO3 perovskites with R = trivalent 4 f ion has challenged the condensed matter research community for almost three decades. A drawback for progress in this direction has been the lack of studies combining physical properties and accurate structural data covering the full nickelate phase diagram. Here we focus on a small region close to the itinerant limit (R = Pr, 1.5 K < T < 300 K), where we investigate the gap opening and the simultaneous emergence of charge order in PrNiO3. We combine electrical resistivity, magnetization, and heat capacity measurements with high-resolution neutron and synchrotron x-ray powder diffraction data that, in contrast to previous studies, we analyze in terms of symmetry-adapted distortion modes. Such analysis allow us to identify the contribution of the different modes to the global distortion in a broad temperature range. Moreover, it shows that the structural changes at the MIT, traditionally described in terms of the evolution of the interatomic distances and angles, appear as abrupt increases of all nonzero mode amplitudes at TMIT = TN ∼ 130 K accompanied by the appearance of new modes below this temperature. A further interesting observation is the existence of a nearly perfect linear correlation between the amplitude of the breathing mode associated to the charge order and the staggered magnetization below the MIT. Our data also uncover a previously unnoticed anomaly at T ∗ ∼ 60 K (∼0.4 × TMIT), clearly visible in the electrical resistivity, lattice parameters and some mode amplitudes. Since phase coexistence is only observed in a small temperature region around TMIT (∼±10 K), these observations suggest the existence of a hidden symmetry in the insulating phase. We discuss some possible origins, among them the theoretically predicted existence of polar distortions induced by the noncentrosymmetric magnetic order [Perez-Mato et al., J. Phys.: Condens. Matter 28, 286001 (2016); Giovanetti et al., Phys. Rev. Lett. 103, 156401 (2009)].
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File name | Size | Description |
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Data_files.zip
MD5md5:39d5839c6941fea386277dc33d48180c
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35.4 MiB | Experimental data files (text or excel format). |
Input+Output_Basireps_SG_221_SG_62.txt
MD5md5:1f305701d0f551657895c8dbfbc06b6e
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3.5 KiB | Amplimodes input (SG Pbnm), text format |
Input+Output_Basireps_SG_221_SG_14.txt
MD5md5:7333e3b0a6958949c1475a4faab071ce
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4.9 KiB | Amplimodes input (SG P21/n), text format |
FullProf_input_data_magn+amplimodes.docx
MD5md5:f14a7010f54fe844fd483c7617b650d3
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31.9 KiB | Detailed output (Amplimodes fits), docx format |
FullProf_input_data_cryst_structure.txt
MD5md5:15febe9f045c6d2e430eb14fb58de9db
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40.8 KiB | Detailed output (Atomic coordinate fits), text format |
Readme.txt
MD5md5:cca68bb2a021c5b573a5d82e8be6ceed
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681 Bytes | Contents of the folder "Data_files.zip" , text format |
2019.0084/v2 (version v2) [This version] | Dec 14, 2019 | DOI10.24435/materialscloud:2019.0084/v2 |
2019.0084/v1 (version v1) | Dec 02, 2019 | DOI10.24435/materialscloud:2019.0084/v1 |